Metallaboranes of the earlier transition metals. An arachno nine-vertex, nine-skeletal electron pair rhenaborane of novel shape: importance of total vertex connectivities in such systems
- 24 April 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 895-896
- https://doi.org/10.1039/b101918j
Abstract
The synthesis and characterization of Cp*2Re2B7H11 provides the first example of an open hypoelectronic metallaborane which is shown to possess an arachno geometry based on a total vertex connectivity identical with that of a canonical arachno nine-vertex, twelve-skeletal electron pair cluster.Keywords
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