Thermolytic reactions of benzotriazinone and isatoic anhydride

Abstract
Benzotriazinone loses nitrogen on thermolysis in solution to give a heterodiene which reacts with dienophiles such as benzyne and p-methoxybenzaldehyde. Isatoic anhydride in hot solvents is attacked nucleophilically by esters with loss of carbon dioxide to give benzoxazinones.

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