Evidence for reversible α-elimination of hydrogen from a tungsten–methyl compound giving a tungsten–methylene–hydride derivative
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 761-762
- https://doi.org/10.1039/c39740000761
Abstract
The reversible reaction[W(η-C5H5)2(PR3)CD3]+⇌[W(η-C5H5)2(CD2PR3)D]+ and related reactions are described; it is proposed that they proceed via a reversible equilibrium W–CH3⇌ W(CH2)H.Keywords
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