A new enantioselective asymmetric synthesis of alkyl t-butylsulphinates
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1670-1672
- https://doi.org/10.1039/c39850001670
Abstract
The reaction of symmetrical sulphites with t-butylmagnesium chloride in the presence of chiral aminoalcohols has been found to proceed in an asymmetric way affording chiral t-butylsulphinates in 40–70% enantiomeric excess.Keywords
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