A Significant Substituent Effect on the Stereochemistry of the Trityl Salt-Catalyzed Michael Reaction
- 5 April 1987
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 16 (4) , 743-746
- https://doi.org/10.1246/cl.1987.743
Abstract
In the presence of a catalytic amount of trityl salts, silyl enol ethers of thioesters react with α-substituted α,β-unsaturated cyclic ketones to afford the corresponding Michael adducts in good yields with excellent lk diastereoselectivities.Keywords
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