Ground and excited state 1,4-addition reactions of some carbohydrate enones
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1286-1287
- https://doi.org/10.1039/c39720001286
Abstract
Highly functionalised branched-chain monosaccharides can be prepared by sensitised irradiation of conjugated enones (1) and (2) in an alcohol whereupon equatorial 1,4-addition of the carbinol is the major event, the adducts so obtained being correlated with the products of ground-state additions.Keywords
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