Novel monodentate spiro phosphorus ligands for rhodium-catalyzed hydrogenation reactions
- 7 February 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 480-481
- https://doi.org/10.1039/b109827f
Abstract
Novel monodentate phosphorus ligands containing the 1,1′-spirobiindane backbone have been synthesized and applied in the asymmetric rhodium-catalyzed hydrogenation of functionalized olefins, providing excellent enantioselectivities (up to 99.3% ee).Keywords
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