Zum Bildungsmechanismus von Vanadium Nitrosyl-Komplexen aus Hydroxylamin:Reversible, intramolekulare Umwandlung eines Nitrosylliganden in einen Hydroxylamido(1 —)-Liganden / On the Mechanism of the Formation of Nitrosylvanadium Complexes from Hydroxylamine: Reversible, Intramolecular Conversion of Coordinated Nitric Oxide to a Hydroxylamido(1—) Ligand
Open Access
- 1 June 1981
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 36 (6) , 683-686
- https://doi.org/10.1515/znb-1981-0606
Abstract
The kinetics and the mechanism of a reversible, intramolecular conversion of a coordinated nitrosyl ligand into a probably O,N-coordinated hydroxylamido(1-) ligand is reported for the complex anion [V(tha)(NO)(H2O)]- (tha = 1,1′,1″-nitrilo-tris-2-propanol). Mechanisms for the formation of nitrosyl complexes of the type {V-N=O}4 generated from hydroxylamine and complexes of vanadium in the oxidation states + V or + III, respectively, are proposed.Keywords
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