Temperature and composition dependence of the tetragonal-orthorhombic distortion in
- 1 May 1987
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 35 (13) , 7191-7194
- https://doi.org/10.1103/physrevb.35.7191
Abstract
We have mapped the temperature and composition dependence of the tetragonal-orthorhombic phase-transition temperature in the high-temperature superconductor using high-resolution powder x-ray diffraction and measurements of the thermal expansion. The maximum volume fraction of ideal diamagnetism occurs in the composition range where is approaching the superconducting transition. In the composition range x>0.20 where no orthorhombic distortion is observed above 12 K, no bulk superconductivity is observed in .
Keywords
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