Photochemistry of bromobiphenyls: steric effects and electron transfer
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 16,p. 1607-1610
- https://doi.org/10.1039/p19750001607
Abstract
Evidence is presented that photolytic fission of the C–Br bonds of bromobiphenyls is preceded by electron transfer. The enhanced rate of photodecomposition of 2-bromobiphenyls is shown to result from the release of steric strain in the excited state.Keywords
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