Interaction of Aminoacyl-tRNA with Bacterial Elongation Factor Tu : GTP Complex: Effects of the Amino Group of Amino Acid Esterified to tRNA, the Amino Acid Side Chain, and tRNA Structure

Abstract
The present investigation was undertaken to see to what extent the a-amino group of the amino acid, the side chain of the amino acid of aminoacyl-tRNA, and th tRNA structure are involved in determining the affinity of aminoacyl-tRNA for bacterial elongation factor Tu-GTP complex. Various aminoacyl-tRNAs, mis aminoacylated tRNAs, and formylated aminoacyl-tRNAs were prepared, and the dissociation constants of the ternary complexes of aminoacyl-tRNA with EF-Tu: GTP were determined by the RNase-resistance assay. The results indicated that the free α-amino group of the amino acids in aminoacyl-tRNA is strongly required for binding with EF-Tu: GTP. In this connection, the biological significance of formylation for Met-tRNAMetf species is discussed.

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