Mass spectrometry of free radicals
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 63, 1342-1348
- https://doi.org/10.1039/tf9676301342
Abstract
The ionization potentials of the CH2OH and (CH3)2N radicals have been determined directly as [graphic ommitted]8.14 ± 0.15 eV and [graphic ommitted]9.42 ± 0.1 eV respectively. The heats of formation of the radicals were [graphic ommitted] –8.4 ± 3 kcal mole–1 and [graphic ommitted]30.3 kcal mole–1 respectively. Calculations have been made of several relevant bond dissociation energies.Keywords
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