Elastomers based on poly(hexafluoropropylene oxide) crosslinked via triazine groups
- 1 September 1994
- journal article
- research article
- Published by Wiley in Macromolecular Chemistry and Physics
- Vol. 195 (9) , 3137-3148
- https://doi.org/10.1002/macp.1994.021950912
Abstract
Poly(hexafluoropropylene oxide), poly(HFPO), networks were prepared from functional polymers by end‐linking via triazine groups. The networks were characterised by NMR spectroscopy and by determination of the number of network chains from the shear modulus, and were shown to contain both triazine crosslinks and imidoylamidine links. The mechanical, thermal and chemical properties of the networks were investigated by a range of techniques. A network formed from fully difunctional poly(HFPO) had excellent elastomeric properties above −15°C, and was thermally stable up to 270°C.Keywords
This publication has 9 references indexed in Scilit:
- The use of model polymer networks to elucidate molecular aspects of rubberlike elasticityPublished by Springer Nature ,2007
- Glass transition temperature as a function of conversion in thermosetting polymersMacromolecules, 1991
- Perfluoroalkylene‐ether triazine elastomersJournal of Polymer Science Part C: Polymer Letters, 1982
- Synthesis of perfluoroalkylether triazine elastomersJournal of Polymer Science Part C: Polymer Letters, 1980
- Anionic Polymerization of Fluorocarbon EpoxidesPublished by American Chemical Society (ACS) ,1977
- Polymers from Hexafluoropropylene Oxide (HFPO)Journal of Macromolecular Science: Part A - Chemistry, 1974
- Polymerization of Perfluoro EpoxidesJournal of Macromolecular Science: Part A - Chemistry, 1972
- Large elastic deformations of isotropic materials IV. further developments of the general theoryPhilosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1948
- The Thermodynamics of a Strained Elastomer. I. General AnalysisJournal of Applied Physics, 1948