Migration of t-butyldimethylsilyl protecting groups
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 11,p. 2762-2764
- https://doi.org/10.1039/p19790002762
Abstract
Isomeric 2′- and 3′-O-t-butyidimethylsilylribonucleoside derivatives (2) and (3) undergo interconversion by a first-order equilibration reaction. This intramolecular reaction takes place particularly readily in methanol solution and in the presence of base.This publication has 2 references indexed in Scilit:
- The synthesis of oligoribonucleotides. II. The use of silyl protecting groups in nucleoside and nucleotide chemistry. VIICanadian Journal of Chemistry, 1978
- The synthesis of oligoribonucleotides—IIITetrahedron, 1967