N5+: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material
Open Access
- 12 July 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (13-14) , 2004-2009
- https://doi.org/10.1002/(sici)1521-3773(19990712)38:13/14<2004::aid-anie2004>3.0.co;2-7
Abstract
Only the third known example of a homoleptic polynitrogen species besides N2 and N3−, the N5+ ion possesses surprising stability and can be isolated on a macroscopic scale as its AsF6− salt. The assigment of the C2v‐symmetric structure (shown schematically) predicted by calculations was supported by IR and Raman as well as 14N and 15N NMR spectroscopic studies of the isotopically labeled product.This publication has 0 references indexed in Scilit: