Stereospecificity and stereochemistry of a thermal sigmatropic [1,5]-shift of an alkyl group
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 18,p. 1168-1169
- https://doi.org/10.1039/c29700001168
Abstract
Thermal isomerization of cis- and trans-6,9-dimethylspiro[4,4]nona-1,3-diene involves a suprafacial, sigmatropic [1,5]-shift of sp3 carbon, with retention of configuration.Keywords
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