The formation of a novel quinquedentate N4O ligand by dioxygen oxidation of trans-(RSSR)-[CoCl2(teta)]ClO4
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 979-980
- https://doi.org/10.1039/c39840000979
Abstract
The reaction of O2 with trans-(RSSR)-[CoCl2(teta)]ClO4 in refluxing MeOH containing base (triethylamine) results in the oxidation of one of the gem-dimethyl substituents to form a quinquedentate N4O ligand with a co-ordinated –CH2OH group.Keywords
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