Five-co-ordinate molybdenum and tungsten complexes, [M(CO)3(PCy3)2], which reversibly add dinitrogen, dihydrogen, and other small molecules
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 61-62
- https://doi.org/10.1039/c39800000061
Abstract
New complexes of molybdenum and tungsten with dinitrogen and other small molecules, trans-[M(CO)3(PCy3)2L](L = N2, H2, C2H4, or SO2), have been synthesized by the reaction of [M(CO)3(cycloheptatriene)] with 2PCy3 in the presence of L; removal of L yields the formally five-co-ordinate species [M(CO)3(PCy3)2].Keywords
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