Effect of a dissolved gas on the homogeneous nucleation pressure of a liquid
- 15 March 1977
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (6) , 2322-2330
- https://doi.org/10.1063/1.434267
Abstract
An isothermal decompression technique has been used to measure the pressure at which homogeneous nucleation of bubbles occurs in solutions of nitrogen in ethyl ether. Droplets of the ethyl ether–nitrogen solution were suspended in a host liquid by flowing the host liquid at a rate which just countered the buoyancy of the droplets. The system was then decompressed until nucleation occurred. The presence of the dissolved nitrogen in the ethyl ether was observed to raise the pressure at which nucleation occurred. The extent of the increase corresponds closely with that which has been previously predicted.Keywords
This publication has 14 references indexed in Scilit:
- Critical state of bubbles in liquid-gas solutionsJournal of Applied Physics, 1975
- Boiling NucleationPublished by Elsevier ,1974
- A Novel Technique for Measuring the Strength of LiquidsThe Journal of the Acoustical Society of America, 1971
- On the Thermodynamics of Nucleation in Weak Gas-Liquid SolutionsJournal of Basic Engineering, 1970
- Generalized reference fugacities for phase equilibrium thermodynamicsChemical Engineering Science, 1965
- Volumetric properties of gas mixtures containing one or more polar componentsAIChE Journal, 1962
- On the Limit of SuperheatJournal of the Physics Society Japan, 1958
- The Fracture of LiquidsJournal of Applied Physics, 1948
- Thermodynamical Calculations of Solubilities of Nitrogen and Hydrogen in Water at High PressuresJournal of the American Chemical Society, 1935
- The Pressure-Volume Relation of Super-heated LiquidsThe Journal of Physical Chemistry, 1922