Crystal radius and enthalpy of hydration of the cyanide ion.
- 1 March 1977
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 33 (3) , 663-669
- https://doi.org/10.1080/00268977700100621
Abstract
On the basis that the (electron density) crystal radius of the ion CN- is 1·77 Å, estimates have been made of the standard enthalpy of hydration of CN-(g) plus gaseous alkali metal ions. The results have been used in the derivation of the total lattice potential energies U POT(MCN) of alkali metal cyanides and other related thermochemical quantities. The following estimates have been made (298·15 K):Keywords
This publication has 12 references indexed in Scilit:
- Ionic radii and enthalpies of hydration of ionsPublished by Springer Nature ,2008
- Ionic radii and enthalpies of hydration of ionsPublished by Springer Nature ,2008
- Lattice potential energies of orthorhombic and cubic cyanides of the alkali metals Enthalpy of formation, ΔH°f(CN−)(g) and solvation, ΔH°solv(CN−)(g) of gaseous cyanide ion. Experimental determination of the enthalpy of solution of crystalline lithium cyanide, ΔH°soln(LiCN)(c), proton affinity of cyanide ion and electron affinity of CN. radicalJournal of Inorganic and Nuclear Chemistry, 1977
- Polymorphic transitions in cyanide crystals and the calculation of the lattice energies of cyanide salts. Thermodynamic parameters for the gaseous cyanide ionJournal of Inorganic and Nuclear Chemistry, 1976
- Photoionization of HCN: The Electron Affinity and Heat of Formation of CNThe Journal of Chemical Physics, 1969
- Crystal radius of the cyanide ionActa Crystallographica, 1961
- Lattice energies and associated properties of some crystalline cyanidesJournal of Inorganic and Nuclear Chemistry, 1960
- Lattice energy of ionic crystalsQuarterly Reviews, Chemical Society, 1956
- Molecular Rotation in Sodium Cyanide and Sodium NitrateThe Journal of Chemical Physics, 1949
- L slichkeit und Ionisation vom Standpunkte der AtomstrukturThe Science of Nature, 1921