Synthesis, stereochemistry, mechanisms of formation, and X-ray crystal structures of enantiomerically pure π-allylpalladium compounds formed via palladium-promoted ring opening of bicyclic alkenes
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 834-836
- https://doi.org/10.1039/c39870000834
Abstract
The synthesis, stereochemistry, mechanisms of formation, and X-ray crystal structures of enantiomerically pure π-allylpalladium compounds (1)–(3) prepared by palladium hydride addition to (1R)-(+)-α-pinene, (1S)-(–)-α- or -β-pinene, and (1S)-(+)-2- or -3-carene respectively are presented.Keywords
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