Die Kristallstruktur eines polynuclearen Silber‐Platin‐Mercaptophosphin‐Komplexes
- 1 January 1969
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 52 (1) , 270-279
- https://doi.org/10.1002/hlca.19690520127
Abstract
Crystals of Pt(S–CH2‐Ch2‐P(C2H5)2)2AgNO3 are orthorhombic, a = 14.814, b = 10.926, c = 12.298 Å, space group Pbon, Z = 4. The structure has been solved by FOURIER methods and refined by full‐matrix least‐squares analysis of three dimensional intensity data, measured on the HILGER & WATTS computer‐controlled 4‐circle diffractometer. The structure consists of infinite chains running along the c‐axis; each silver atom is coordinated almost linearly to two sulphur atoms belonging to the square‐planar coordination spheres of two different platinum atoms.Keywords
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