Exchange interaction in hybrid spin systems: chloro-meso-tetraphenylporphyrinatochromium(III) derivatives ligated with 3- and 4-(N-oxy-N-tert-butylamino)pyridines
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 447-448
- https://doi.org/10.1039/c39940000447
Abstract
The 3d electrons of chromium(III) and the unpaired electron of the nitroxide radical interact ferro- and antiferro-magnetically in chloro-meso-tetraphenylporphyrinatochromium(III) ligated with 3- and 4-(N-oxy-N-tert-butylamino)pyridines to produce quintet and triplet ground states, respectively.Keywords
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