Abstract
The reduction of erbium triiodide with caesium in the presence of carbon yielded two new ternary reduced iodides of erbium as black single crystals, Cs[Er6C]I12 and Cs[Er10(C2)2]I18, containing the monomeric unit [Er6C] and the dimeric unit [Er10(C2)2] composed of two [Er6(C2)] octahedra sharing a common edge, respectively.

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