Synthesis and crystal structures of two new reduced iodides of erbium with isolated monomeric and dimeric clusters, Cs[Er6C]I12 and Cs[Er10(C2)2]I18
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 1320-1321
- https://doi.org/10.1039/c39920001320
Abstract
The reduction of erbium triiodide with caesium in the presence of carbon yielded two new ternary reduced iodides of erbium as black single crystals, Cs[Er6C]I12 and Cs[Er10(C2)2]I18, containing the monomeric unit [Er6C] and the dimeric unit [Er10(C2)2] composed of two [Er6(C2)] octahedra sharing a common edge, respectively.Keywords
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