Attractive steric interactions within molecules. The masking of effects in meta-disubstituted benzenes by buttressed repulsive interactions
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 1077-1078
- https://doi.org/10.1039/c39940001077
Abstract
The attractive steric interaction between the groups in a sidechain to a benzene ring and a meta-substituent is usually more than offset by the repulsive interaction of the sidechain with the ortho-hydrogen atom which is buttressed by the meta-substituent.Keywords
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