Reactions of molecular CaF2 with [(C5Me5)TiF3] and [(C5Me4Et)TiF3]: symbiosis between ionic solids and organometallic compounds
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 13,p. 2215-2216
- https://doi.org/10.1039/a702807e
Abstract
The reaction between [(C 5 Me 5 )TiF 3 ] or [(C 5 Me 4 Et)TiF 3 ] respectively in the presence of CaF 2 (prepared in situ) resulted in the formation of [{(C 5 Me 5 )TiF 3 } 4 CaF 2 ] 1 or [{(C 5 Me 4 Et)TiF 3 } 4 CaF 2 ] 2, an X-ray study of compound 2 showed it to possess a core analogous to a crown ether.Keywords
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