Transition between Concerted and Stepwise Dissociative Electron Transfers. An Example of How a Change of Temperature May Trigger a Change in Mechanism in Electrochemical Experiments
- 1 November 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 119 (47) , 11546-11547
- https://doi.org/10.1021/ja9726062
Abstract
No abstract availableThis publication has 14 references indexed in Scilit:
- Concerted and Stepwise Dissociative Electron Transfers. Oxidability of the Leaving Group and Strength of the Breaking Bond as Mechanism and Reactivity Governing Factors Illustrated by the Electrochemical Reduction of α-Substituted AcetophenonesJournal of the American Chemical Society, 1997
- Photoinduced electron transfer double fragmentation: an oxygen-mediated radical chain process in the co-fragmentation of substituted pinacol donors with carbon tetrachlorideJournal of Photochemistry and Photobiology A: Chemistry, 1996
- Concerted Bimolecular Substitution Reactions of Anilino ThioethersJournal of the American Chemical Society, 1995
- Passage from Concerted to Stepwise Dissociative Electron Transfer as a Function of the Molecular Structure and of the Energy of the Incoming Electron. Electrochemical Reduction of Aryldialkyl Sulfonium CationsJournal of the American Chemical Society, 1994
- Electron transfer, bond breaking, and bond formationAccounts of Chemical Research, 1993
- Controlling factors of stepwise versus concerted reductive cleavages. Illustrative examples in the electrochemical reductive breaking of nitrogen-halogen bonds in aromatic N-halosultamsJournal of the American Chemical Society, 1993
- Dissociative electron transfer. New tests of the theory in the electrochemical and homogeneous reduction of alkyl halidesJournal of the American Chemical Society, 1992
- Supramolecular entropy gains: simple and superstructured iron porphyrinsThe Journal of Physical Chemistry, 1992
- Electron transfer and bond breaking. Examples of passage from a sequential to a concerted mechanism in the electrochemical reductive cleavage of arylmethyl halidesJournal of the American Chemical Society, 1992
- A simple model for the kinetics of dissociative electron transfer in polar solvents. Application to the homogeneous and heterogeneous reduction of alkyl halidesJournal of the American Chemical Society, 1987