Synthesis of unsymmetrical disulphides
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 680-683
- https://doi.org/10.1039/p19720000680
Abstract
The synthesis of Unsymmetrical disulphides by cleaving sulphenamides and sulphenic esters with alkyl- and arylthiosilanes and thiols is reported. Alkyl phenyl disulphides and unsymmetrical diaryl disulphides can be prepared conveniently and in 80–90% yield by the interaction of methyl benzenesulphenate and a thiol. Unsymmetrical dialkyl disulphides result from dimethyl or diethyl disulphide and a thiol.Keywords
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