Hydrogen abstraction by perfluoroethyl radicals from methylfluorosilanes
- 1 August 1976
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 54 (15) , 2359-2364
- https://doi.org/10.1139/v76-336
Abstract
Arrhenius parameters have been measured for hydrogen abstraction by C2F5 radicals (produced from the photolysis of perfluoropropionic anhydride) from methylfluorosilanes and tetramethylsilane.[Formula: see text]The results are discussed in relation to those of similar reactions involving the CF3 and the CH3 radical, and interpreted in terms of polar effects.Keywords
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