Spin Dipole—Dipole Interaction in O2

15 January 1965

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 42 (2) , 622-630
https://doi.org/10.1063/1.1695982

Abstract

The electron spin dipole—dipole interaction in O2 is calculated nonempirically by the use of several approximate wavefunctions of the HL and LCAO—MO types. It is pointed out that the experimental value determined by Tinkham and Strandberg can hardly be explained by simple LCAO‐type approximations; the calculated value would agree with the experiment only if the wavefunctions of this molecule were almost completely ionic.

Keywords

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