Natural polypeptides in left‐handed helical conformation A circular dichroism study of the linker histones’ C‐terminal fragments and β‐endorphin

Abstract
Circular dichroism has been used to investigate the histone HI and H5 C-terminal fragments and β-endorphin conformation. It has been shown that in aqueous solution these polypeptides preferably adopt the left-handed helical conformation of the poly-l-proline II type. A break in the linear temperature dependence of the CD value was found in the temperature interval between 50 and 55°C. It was proposed to be due to non-cooperative disordering of the conformation caused by the destruction of the hydration shell.

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