Electron spin resonance studies of oxidation. Part VIII. Elimination reactions of some hydroxyalkyl radicals
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 849-852
- https://doi.org/10.1039/j29660000849
Abstract
The electron spin resonance spectra of radicals generated by the one-electron oxidation of some diols and related compounds are described and discussed. Evidence is adduced that radicals of the type HO–Ċ[graphic omited]–C[graphic omited]–X, where X is a good leaving-group, readily undergo elimination to give OC[graphic omited]–Ċ. The spectrum of the radical ·CH2CHO is discussed.Keywords
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