DESULFURIZATION OF 2-THIOURIDINES BY DIPOTASSIUM DIAZENEDICARBOXYLATE
- 5 October 1982
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 11 (10) , 1621-1624
- https://doi.org/10.1246/cl.1982.1621
Abstract
The reaction of 5-methoxycarbonylmethyl-2-thiouridine (la) with dipotassium diazenedicarboxylate and with N2H4–H2O2 afforded l-(β-D-ribofuranosyl)-5-methoxycarbonylmethyl-4-(lH)-pyrimidinone (3a) in good yields, suggesting that the reaction involves diimide. On treatment with H2O2, la also gave 3a.Keywords
This publication has 7 references indexed in Scilit:
- Studies on nucleosides and nucleotides. X. desulfurization of 2′,3′-0-Isopropylidene-2-thiouridines by dibenzoyldiazeneTetrahedron Letters, 1982
- Preparation of 2-pyrimidinone nucleosides from uracil nucleosidesCollection of Czechoslovak Chemical Communications, 1977
- Studies of nucleosides and nucleotides—LIVTetrahedron, 1972
- Optical Properties of Thiopyrimidine NucleosidesCHEMICAL & PHARMACEUTICAL BULLETIN, 1969
- Nucleosides. XLVII. Syntheses of some N4-substituted derivatives of 1-.beta.-D-arabinofuranosylcytosine and -5-fluorocytosineJournal of Medicinal Chemistry, 1968
- Zur Chemie des DiiminsAngewandte Chemie, 1965
- Formation of Phenyldiimide and Phenyl Radical by Heterolysis of N-Phenyl-N'-benzoyldiimide1The Journal of Organic Chemistry, 1965