Living anionic polymerization of phosphorus-bridged, [1]ferrocenophanes: synthesis and characterization of poly(ferrocenylphosphine) homopolymers and block copolymers
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 22,p. 2589-2590
- https://doi.org/10.1039/cc9960002589
Abstract
The phosphorus-bridged [1]ferrocenophane Fe(η-C5H4)2-PPh undergoes living anionic ring-opening polymerization at 25 °C in THF using BunLi as initiator to yield monodisperse poly(ferrocenylphosphines) of controlled molecular mass and novel block copolymers with potentially coordinating phosphorus atoms in one segment.Keywords
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