Electron Diffraction Study of the Toluene Molecular Geometry

Abstract
On the basis of an electron diffraction analysis, the following structural information was obtained on vapour phase toluene molecules: rg(C C)mean 1.399 ± 0.002 Å, rg(C-C) 1.511 ± 0.008 Å, the mean length of the C-H bonds is 1.117 ± 0.005 Å (rg). The methyl C-H bonds are at least 0.020 Å longer than the phenyl C-H bonds which are not longer than those in benzene

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