RS-verbrückte Carbonyl-Wolfram-Komplexe / RS-Bridged Carbonyl Tungsten Complexes

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Abstract
Photochemical reaction of thiols RSH or disulfides RSSR with W(CO)6 gives dinuclear complexes [W(CO)4(μ2-SR)2]2 and trinuclear open chain compounds (CO)4(μ2-SR)2W(CO)2(μ2-SR)2W(CO)4. Syntheses and properties, including solid state structures as determined by X-ray methods are described.