The Molecular Structure, Dipole Moment, and g Factor of Ozone from Its Microwave Spectrum
- 1 May 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (5) , 851-855
- https://doi.org/10.1063/1.1699045
Abstract
Four low‐J rotational transitions of 0316 have been measured in the region from 42 to 118 kmc. The rotational spectroscopic constants found are A = 106,530.0±1.1 Mc, B = 13,349.06±0.06 Mc, C = 11,834.3±1.1 Mc. The oxygen nuclei form an isosceles triangle with an apex angle of 116°49′±30′, and the two equal internuclear distances are 1.278±0.003A. From the Stark splitting of the 20,2→11,1 transition the dipole moment is 0.53±0.02 debye. Zeeman splittings of this transition show that ozone is not significantly paramagnetic.Keywords
This publication has 15 references indexed in Scilit:
- Microwave Spectroscopy in the Region from Two to Three Millimeters, Part IIPhysical Review B, 1951
- Rotational Magnetic Moments in Polyatomic MoleculesPhysical Review B, 1951
- Measurements of electric dipole moments by a microwave resonance methodZeitschrift für angewandte Mathematik und Physik, 1950
- Molecular Dipole Moments and Stark Effects. II. Stark Effects in OCSPhysical Review B, 1950
- A Reinvestigation of the Vibration Spectrum of OzoneThe Journal of Chemical Physics, 1948
- On the Structure of OzoneThe Journal of Chemical Physics, 1947
- A Microwave SpectrographPhysical Review B, 1947
- The assignment of the vibrational frequencies, and the force field of the ozone moleculeTransactions of the Faraday Society, 1945
- The Molecular Structure of OzoneJournal of the American Chemical Society, 1943
- The Dipole Moments and Structures of Ozone, Silicobromoform and DichlorogermaneJournal of the American Chemical Society, 1939