Asymmetrische Katalysen, 71 / Asymmetric Catalyses, 71
Open Access
- 1 September 1991
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 46 (9) , 1145-1148
- https://doi.org/10.1515/znb-1991-0902
Abstract
The enantioselective hydrosilylation of acetophenone with diphenylsilane in the solvents toluene and CCl4 was catalysed with a [Rh(COD)Cl]2/2-pyridineoxazoline catalyst. The “CCl4-effect” (higher enantioselectivity and reactivity) was already confirmed with stoichiometric quantities of CCl4 with respect to the Rh-catalyst. The influence of other halogenated solvents on the hydrosilylation was investigated.Keywords
This publication has 0 references indexed in Scilit: