α-Thiocyanation of Carbonyl and β-Dicarbonyl Compounds Using (Dichloroiodo)benzene−Lead(II) Thiocyanate
- 24 February 2001
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 66 (6) , 2019-2023
- https://doi.org/10.1021/jo001504i
Abstract
The combination reagent (dichloroiodo)benzene and lead(II) thiocyanate in dichloromethane effects oxidation of various enol silyl ethers, ketene silyl acetals, and beta-dicarbonyl compounds, thereby providing an efficient and convenient method for alpha-thiocyanation of carbonyl and beta-dicarbonyl compounds.Keywords
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