Hydrothermal assembly and structural characterisation of one- and two-dimensional organic/inorganic hybrid materials constructed from diphosphopentamolybdate(VI) clusters and {Cu(en)}2+ complex groups

Abstract
Three novel low-dimensional organic/inorganic hybrid materials, assembled hydrothermally, are constructed from diphosphopentamolybdate(VI) clusters linked through {Cu(en)}2+ groups; the initial Mo/Cu and Mo/en ratios and the use of F ions control the connectivity between the phosphomolybdate clusters and {Cu(en)}2+ groups, and hence the dimensionality of the solid architectures.

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