The Crystal and Molecular Structure of meso-(2S,4s,6R)-2,4,6-Heptanetriol
- 1 March 1974
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 47 (3) , 545-547
- https://doi.org/10.1246/bcsj.47.545
Abstract
The crystal structure of meso-(2S,4s,6R)-2,4,6-heptanetriol has been determined by means of X-ray methods. The crystal belongs to monoclinic system (space group Ic), with four molecules in a unit cell with dimensions of a=8.133, b=9.374, c=11.248 Å, and β=93.24°. The structure was solved by three-dimensional Patterson and trial-and-error methods. The final R factor was 0.076. The molecule has the GTT\barG conformation, and all of the OH groups are linked together by intermolecular hydrogen bonds.This publication has 9 references indexed in Scilit:
- Tacticity of Poly(vinyl alcohol) Studied by Nuclear Magnetic Resonance of Hydroxyl ProtonsMacromolecules, 1972
- NMR spectra of poly(vinyl acetate) and poly(vinyl alcohol)Journal of Polymer Science Part B: Polymer Letters, 1967
- Separation and characterization of stereoisomeric 2,4,6‐triacetoxyheptane and 2,4,6‐heptanetriolJournal of Polymer Science Part B: Polymer Letters, 1966
- NMR study of model compounds of vinyl polymersJournal of Polymer Science Part A-1: Polymer Chemistry, 1966
- The preparation and some properties of highly stereoregular poly(vinyl alcohol)sJournal of Polymer Science Part B: Polymer Letters, 1966
- A new route to stereoregular poly(vinyl alcohols)Journal of Polymer Science Part B: Polymer Letters, 1965
- Tacticity of poly(vinyl alcohol) and poly(vinyl trifluoroacetate) by NMRJournal of Polymer Science Part B: Polymer Letters, 1965
- Vibration spectra of polyvinyl acetate and some model substancesCollection of Czechoslovak Chemical Communications, 1963
- Isotactic polyvinyl alcoholJournal of Polymer Science, 1962