Synthetic Studies on a Cyclic Hexadepsipeptide GE3: Stereoselective Construction of the Acyl Side Chain Segment

Abstract
Stereoselective synthesis of the acyl side chain segment 2 of GE3 (1), a potent inhibitor of cell progression of the cell cycle from the G1 to S phase, has been achieved by using Sharpless’ asymmetric dihydroxylation and Evans’ and Paterson’s stereoselective aldol methodologies.

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