Electron spin resonance of transition metal ions in calcium tartrate tetrahydrate host lattice I. Mn2+, Cu2+, and Ni2+ as dopants

15 October 1973

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 59 (8) , 3981-3987
https://doi.org/10.1063/1.1680588

Abstract

The electron spin resonance of Mn²⁺, Cu²⁺, and x‐irradiated Ni²⁺ doped calcium tartrate tetrahydrate single crystals was studied. This and earlier results were discussed together in the light of the known crystal structure of the host lattice. The nickel center was interpreted as the d⁷ Ni³⁺ ion. A possible doping mechanism for transition metal ions in calcium tartrate tetrahydrate was suggested.

Keywords

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