Superionic Conduction in AgCrS2 and AgCrSe2

Abstract
Ionic and electronic conductivity has been measured in and . Ionic conductivity was measured by using as a blocking electrode for electronic conduction. Transference numbers were confirmed by cells of the type . Ionic conductivities were for and , respectively, at room temperature. The conductivity of increases abruptly at ∼170°C to ∼1 (Ω‐cm)−1. A transition at this temperature was observed by DSC.

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