Preparation and Characterization of Pseudohalogeno(methyl)germanes and Related Compounds

Abstract
Synthetic routes to the series of pseudohalogeno(methyl)germanes, MeGeH2Ps and MeGePs3 (Ps = N3, CN, NCO, NCS), and the related compounds MeGeH2OAc and Ge(N3)4 are discussed. The compounds are characterized by their molecular weights, mass spectra, 1H n.m.r. spectra and cleavage reactions. Their i.r. and Raman spectra are assigned as further confirmation of their structures.

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