Radical addition reactions of alkenylsilanes
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 2439-2442
- https://doi.org/10.1039/j29710002439
Abstract
It has been found that chloroform and carbon tetrachloride add to both trimethyl- and triphenyl-allylsilane. The relative reactivities of the double bond in three series of alkenylsilanes, R3Si·[CH2]n·CHCH2(R = Me, Ph, or Cl) toward addition by the trichloromethyl radical have been determined, and the relative reactivities of vinyl- and allyltrimethylsilane toward free radical addition by n-dodecanethiol have been investigated. The factors influencing the reactivities of the various alkenylsilanes toward radical addition reagents are discussed.Keywords
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