Salt effects in the base‐catalyzed polymerization of unsaturated amide compounds. II. Polymerization of p‐vinylbenzamide and acrylamide
- 1 September 1968
- journal article
- research article
- Published by Wiley in Journal of Polymer Science Part A-1: Polymer Chemistry
- Vol. 6 (9) , 2477-2487
- https://doi.org/10.1002/pol.1968.150060905
Abstract
In the presence of a variety of inorganic salts, p‐vinylbenzamide underwent vinyl‐type polymerization by anionic initiators to form the polystyrene derivative, whereas in dimethyl sulfoxide as solvent the aromatic polyamide was always obtained through a proton‐transfer mechanism regardless of the presence of the salts. magnified image In the presence of of the salts, acrylamide is generally polymerized to the polyamide through a proton transfer reaction.Keywords
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