The resolution of [Tris{cis-Diydroxybisethylene Diaminecobalt(III)}cobalt(III)] Nitrate
- 1 January 1958
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 11 (4) , 426-432
- https://doi.org/10.1071/ch9580426
Abstract
The resolution of [tris{cis-dihydroxybisethylenediaminecobalt(II)}cobalt(III)] nitrate (hexol nitrate) into four of the eight theoretically possible optical isomers using potassium d- and l-antimonyl tartrate is described. The reactions involved in the formation of the optically active isomers of the hexol ion show less stereospecificity than those of similar complexes studied by earlier investigators.Keywords
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