Magnetic properties of high purity yttrium, lanthanum, and lutetium and the effects of impurities on these properties
- 1 September 1973
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 59 (5) , 2451-2463
- https://doi.org/10.1063/1.1680357
Abstract
Magnetic susceptibility measurements have been carried out on single and polycrystalline specimens of lutetium between 1.5 and 300 °K by the Faraday method. Its susceptibility was found to be paramagnetic and almost independent of temperature. A broad maximum centered at approximately 120 °K was found. Due to the discrepancies in past results of yttrium and lanthanum, their susceptibilities were also measured. Yttrium and lutetium were found to have χa greater than χc. Provided the specimens were of high purity, the relationship χpoly = (2/3)χa + (1/3)χ was well obeyed. Oxygen and hydrogen were found in general to lower the susceptibilities of these metals. The presence of an fcc phase in lanthanum was found to increase its susceptibility relative to a dhcp phase. An estimate of the susceptibility of pure fcc lanthanum is given.Keywords
This publication has 11 references indexed in Scilit:
- Magnetic properties of high purity scandium and the effect of impurities on these propertiesThe Journal of Chemical Physics, 1973
- The effect of impurities, particularly hydrogen, on the lattice parameters of the “ABAB” rare earth metalsJournal of the Less Common Metals, 1971
- Preparation of lanthanide single crystals; praseodymium, neodymium, and lutetiumJournal of Crystal Growth, 1971
- Neutron Diffraction and Susceptibility Study of Dilute La-Rare-Earth AlloysPhysical Review B, 1968
- Anomaly in the magnetic susceptibility of yttriumPhysics Letters A, 1968
- Simultaneous determination of oxygen and nitrogen in metals by carrier-gas fusion extractionAnalytical Chemistry, 1967
- The magnetic susceptibility and electrical resistivity of yttriumProceedings of the Physical Society, 1965
- A Method for Growing Rare-Earth Single CrystalsJournal of Applied Physics, 1963
- The Magnetic Susceptibilities of Lanthanum, Cerium, Praseodymium, Neodymium and Samarium, from 1.5 K to 300 KProceedings of the Physical Society. Section B, 1957
- Kinetics of the Reaction of Hydrogen with ZirconiumJournal of the Electrochemical Society, 1954