Compton scattering studies of electron correlation effects in chromium

Abstract
The (100), (110) and (111) direction Compton profiles of chromium have been measured with both 412 keV and 60 keV gamma -radiation. When compared with the augmented plane-wave (APW) or linear combination of atomic orbitals band models, all three profiles show an expansion of the electron density distribution attributed to electron-electron correlation and most marked along the (111) nearest-neighbour direction. A new method of calculating anisotropic correlation effects in Compton profiles, which is based on the three-dimensional APW density of states, is reported and shown to reconcile experiment and theory.